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喷淋工艺处理PVC塑料生产废气

文章出处:http://www.cnlwz.com/Products/hxtklxfhs.html作者:启脉环保责任编辑:pvc废气处理设备人气:-发表时间:2018-01-22 15:50【

采用喷淋工艺处置PVC塑料消费废气,将专利的吸收液与改型的喷淋塔相结合,在中试成功的根底上停止了实践工业化使用。使用后果标明:采用该工艺处置某PVC塑料消费企业的消费废气,吸收液在喷淋塔循环液中所占体积分数爲15%时,废气中各净化物目标的去除率达85%以上,关于难处置的苯系物也能较好地去除;处置后废气中各净化物目标的含量满足GB14554—1993《恶臭净化物排放规范》和DB44/27—2001《大气净化物排放限值》的要求;该工艺安装运转费用较低,仅爲电费和大批药剂费用,吸收液可循环运用,设备颐养及维护复杂,可满足市场需求。

关于中小型企业,在废气管理方面的预算无限,面对高额的设备投资及运转本钱,这些企业往往显得力所能及。本任务采用喷淋工艺处置PVC塑料消费废气,将专利的吸收液与改型的喷淋塔相结合,获得了较好的处置效果,且设备复杂、维护方便、运转费用低,可满足市场需求。

1 实验局部

1.1 喷淋工艺的流程和设备

爲了确保处置效果,使废气中的极性和非极性无机成分均被充沛吸收,本工艺采用两台自主设计的改型的喷淋塔串联运用。风机安顿于两塔之间,以避免其被油性气体净化腐蚀,同时保证抽风效果。经过(聚丙烯)PP管道集中搜集的PVC塑料消费废气首先进入1#喷淋塔,在极性吸收液的作用下吸收极性无机分子,停止除油、除烟尘污染处置;处置后的废气经过风机进入2#喷淋塔,在非极性吸收液的作用下吸收非极性无机分子,停止除异味污染处置,达标排放。

喷淋塔是药剂喷淋处置工艺中的关键设备。针对PVC塑料消费废气,设计采用PP材质的喷淋塔。喷淋塔外部由隔层隔开。圆柱体塔身共分爲4层:底层爲循环液槽;向上第2~4层爲填料层,每层填充少量PP材质的环保球(多面体空心球),以增大比外表积;第3和第4层亦爲喷淋层,每层装有少量的喷头,循环泵将底层的循环液抽至第3和第4层,由喷头高速向下喷出,向下喷淋出的循环液与向下流动的废气在环保球上充沛接触,并发作吸附。喷淋塔顶的部锥体构造中亦填充有少量的环保球,作爲除雾层运用。综合思索处置本钱和废气污染效率,废气在塔内的停留工夫确定爲3~4 s。依据废气量的大小及废气成分的复杂水平,确定喷淋塔的尺寸规格。普通来说,关于2×104~6×104 m3/h的废气量,采用内径2.0~3.5 m、高3.5~5.2 m的喷淋塔。

中试时采用内径1.0 m、高3.0 m的两台喷淋塔串联处置风量爲6 000 m³/h的广州宏仁企业集团宏信三厂PVC塑料消费废气。中试设备照片见图1,从右至左顺次爲1#喷淋塔、风机、2#喷淋塔。

1.2 吸收液的选择

喷淋塔所用吸收液爲本课题组分配的专利商品——JYSW-01型极性吸收液和JYSW-02型非极性吸收液。这两种吸收液是采用先进的萃取技术从纯自然玉米中提取糖苷类活性物质,再参加羧酸钠盐类作爲外表活性剂制成的。该吸收液可与水以恣意比例互溶,在气-液对流界面经过分子间作用力与无机分子迅速发作多种物理化学进程,对芬芳族类无机物具有共同的处置才能。

1#喷淋塔循环液中添加JYSW-01型极性吸收液,2#喷淋塔循环液中添加JYSW-02型非极性吸收液。进入循环液中的无机物比水轻,悬浮于循环液的外表。其中:与空气接触局部被氧化并聚集,可以固体形状捞出,用来做动物肥料;

另一局部在外部经长工夫生化反响被降解。循环液不需改换,并能自动补水,只需活期补加相应吸收液即可。
1.3 剖析办法

喷淋工艺安装运转一周后,采用消费的CD-2H型恒流大气采样器对1#喷淋塔进气口(处置前)和2#喷淋塔出气口(处置后)的废气停止采样。采用活性炭吸附—二硫化碳解吸气相色谱法测定苯、甲苯和二甲苯的质量浓度;采用气相色谱法测定总VOCs和非甲烷总烃的质量浓度;采用北京北信将来电子科技中心消费的HJ05-LB-4110型烟尘测试仪测定颗粒物质量浓度;采用三点比拟式臭袋法测定臭气浓度。依据测定后果计算各净化物的去除率。

 

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